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Pouring Oil Into Vinegar Stock PhotoBottle,Color Image,Cooking Oil,Corn Oil,Food,Glass - Material,Healthy Lifestyle,Jar,No People,Photography,Pouring,Salad Dressing,Separation,Two Objects,Vertical,Vinaigrette Dressing,VinegarPhotographer PHOTO RESEARCHERS, INC.Collection: Science Source Oil and vinegar. The oil will separate to the top layer because it is less dense than the darker vinegar. These liquids are called immiscible, but when shaken they form an emulsion, a mixture of the two. After some time the oil and vinegar will once again separate into two distinct layers.